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Photosensitive Schottky barrier diode behavior of a semiconducting Co(III)-Na complex with a compartmental Schiff base ligand

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dc.contributor.authorGhosh, Kousik
dc.contributor.authorSil, Sayantan
dc.contributor.authorRay, Partha Pratim
dc.contributor.authorOrtega-Castro, Joaquin
dc.contributor.authorFrontera, Antonio
dc.contributor.authorChattopadhyay, Shouvik
dc.date.accessioned2024-09-10T13:10:31Z
dc.date.available2024-09-10T13:10:31Z
dc.date.issued2019-10-30
dc.description.abstractThe opto-electronic properties of an X-ray characterized, end-to-end azide bridged cobalt(III)-sodium complex, [(N-3)CoLNa(N-3)](n), have been investigated in detail. The complex is found to be a direct semiconductor material as confirmed by determining the band gap of this complex by experimental as well as theoretical studies. The complex has also been used to construct a photosensitive Schottky device. Optical conductivity, calculated from the DFT study, has been used to analyze how the conductivity of the material changes upon illumination. The electrical conductivity and concomitantly, the photoconductivity of the material increase as a consequence of photon absorption.en
dc.description.sponsorshipK. G. expresses his gratitude to UGC, India, for awarding a Senior Research Fellowship. Crystallographic data was collected at the DST-FIST, India funded Single Crystal Diffractometer Facility at the Department of Chemistry, Jadavpur University. P. P. R. gratefully acknowledges the financial support of this work by SERB-DST, Govt. of India (Sanction No. EMR/2016/005387, Dated -24.07.2017). AF thanks MINECO/AEI of Spain (Project CTQ2017-85821-R, FEDER funds) for financial support. We also thank the CTI (UIB) for computational facilities.es_ES
dc.format.number60es_ES
dc.format.page34710-34719es_ES
dc.format.volume9es_ES
dc.identifier.citationGhosh K, Sil S, Ray PP, Ortega-Castro J, Frontera A, Chattopadhyay S. Photosensitive Schottky barrier diode behavior of a semiconducting Co(III)-Na complex with a compartmental Schiff base ligand. RSC Adv. 2019 Oct 30;9(60):34710-9.en
dc.identifier.doi10.1039/c9ra06354d
dc.identifier.e-issn2046-2069es_ES
dc.identifier.journalRSC Advanceses_ES
dc.identifier.otherhttp://hdl.handle.net/20.500.13003/9652
dc.identifier.pubmedID35530669es_ES
dc.identifier.scopus2-s2.0-85074717479
dc.identifier.urihttps://hdl.handle.net/20.500.12105/22802
dc.identifier.wos498844000004
dc.language.isoengen
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.publisherversionhttps://dx.doi.org/10.1039/c9ra06354den
dc.rights.accessRightsopen accessen
dc.rights.licenseAttribution-NonCommercial 3.0 Unported*
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/*
dc.titlePhotosensitive Schottky barrier diode behavior of a semiconducting Co(III)-Na complex with a compartmental Schiff base liganden
dc.typeresearch articleen
dspace.entity.typePublication
relation.isPublisherOfPublicationf873b730-a584-43b3-9018-d156aa9d413f
relation.isPublisherOfPublication.latestForDiscoveryf873b730-a584-43b3-9018-d156aa9d413f

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