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Enhanced Photosensitive Schottky Diode Behavior of Pyrazine over 2-Aminopyrimidine Ligand in Copper(II)-Phthalate MOFs: Experimental and Theoretical Rationalization

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dc.contributor.authorHossain, Anowar
dc.contributor.authorDey, Arka
dc.contributor.authorSeth, Saikat Kumar
dc.contributor.authorRay, Partha Pratim
dc.contributor.authorBallester, Pablo
dc.contributor.authorPritchard, Robin G
dc.contributor.authorOrtega-Castro, Joaquin
dc.contributor.authorFrontera, Antonio
dc.contributor.authorMukhopadhyay, Subrata
dc.date.accessioned2024-09-06T09:56:44Z
dc.date.available2024-09-06T09:56:44Z
dc.date.issued2018-08
dc.description.abstractTwo novel Cu(II)-based metal-organic frameworks [C40H34Cu2N6O18 (1) and C20H18CuN2O10 (2)] have been synthesized using 2-ammopyrimidine or pyrazine ligands and phthalate ion and characterized spectroscopically and by X-ray single-crystal diffraction. Both 1 and 2 show electrical conductivity and photosensitivity, evidencing their potentiality in optoelectronic device applications. Experimental and theoretical investigations revealed that the electrical conductivity under irradiation of visible light increases compared to that under dark condition (photosensitive Schottky barrier diode behavior), especially in complex 2. Both 1 and 2 have been successfully applied in technologically challenging thin-film active devices.en
dc.description.sponsorshipA.H. gratefully acknowledges the University Grants Commission (New Delhi) for a senior research fellowship. S.M. and P.P.R. are grateful to the UPE II program of Jadavpur University sanctioned by the University Grants Commission, New Delhi, for financial support for this work. S.K.S. is grateful to SERB-DST for Overseas Postdoctoral Fellowship (SB/OS/PDF-524/2015-16). P.B. acknowledges Gobierno de Espana MINECO (CTQ2014-56295-R and CTQ2017-84319-P), Severo Ochoa Excellence Accreditation (2014-2018 SEV-2013-0319), FEDER funds, Generalitat de Catalunya/CERCA Program, and AGAUR (2017 SGR 1123). A.F. acknowledges MINECO/AEI of Spain (projects CTQ2014-57393-C2-1-P and CTQ2017-85821-R, FEDER funds) for financial support. The authors acknowledge Centre de Tecnologies de la Informacio (CTI) at the UIB for computational facilities.es_ES
dc.format.number8es_ES
dc.format.page9160-9171es_ES
dc.format.volume3es_ES
dc.identifier.citationHossain Anowar, Dey Arka, Seth Saikat Kumar, Ray Partha Pratim, Ballester Pablo, Pritchard Robin G., et al. Enhanced Photosensitive Schottky Diode Behavior of Pyrazine over 2-Aminopyrimidine Ligand in Copper(II)-Phthalate MOFs: Experimental and Theoretical Rationalization. ACS Omega. 2018 Aug;3(8):9160-9171.en
dc.identifier.doi10.1021/acsomega.8b01111
dc.identifier.issn2470-1343
dc.identifier.journalAcs Omegaes_ES
dc.identifier.otherhttp://hdl.handle.net/20.500.13003/9177
dc.identifier.pubmedID31459050es_ES
dc.identifier.scopus2-s2.0-85051730671
dc.identifier.urihttps://hdl.handle.net/20.500.12105/22635
dc.identifier.wos444182900057
dc.language.isoengen
dc.publisherAmerican Chemical Society (ACS)
dc.relation.publisherversionhttps://dx.doi.org/10.1021/acsomega.8b01111en
dc.rights.accessRightsopen accessen
dc.rights.licenseAttribution-NonCommercial 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.titleEnhanced Photosensitive Schottky Diode Behavior of Pyrazine over 2-Aminopyrimidine Ligand in Copper(II)-Phthalate MOFs: Experimental and Theoretical Rationalizationen
dc.typeresearch articleen
dspace.entity.typePublication
relation.isPublisherOfPublication226dc880-a160-4773-8f02-d8d2680f07d3
relation.isPublisherOfPublication.latestForDiscovery226dc880-a160-4773-8f02-d8d2680f07d3

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