2026-04-29T07:24:23Zhttps://repisalud.isciii.es/rest/oai/request

oai:repisalud.isciii.es:20.500.12105/250902025-12-18T13:01:39Zcom_20.500.12105_2327com_20.500.12105_2290col_20.500.12105_16991

00925njm 22002777a 4500 dc Barrio, Jesús Del author Liu, Ji author Brady, Ryan A author Tan, Cindy S Y author Chiodini, Stefano author Ricci, Maria author Fernández-Leiro, Rafael author Tsai, Ching-Ju author Vasileiadi, Panagiota author Di Michele, Lorenzo author Lairez, Didier author Toprakcioglu, Chris author Scherman, Oren A author 2019-09-11 The binding of imidazolium salts to cucurbit[8]uril, CB[8], triggers a stepwise self-assembly process with semiflexible polymer chains and crystalline nanostructures as early- and late-stage species, respectively. In such a process, which involves the crystallization of the host-guest complexes, the guest plays a critical role in directing self-assembly toward desirable morphologies. These include platelet-like aggregates and two-dimensional (2D) fibers, which, moreover, exhibit viscoelastic and lyotropic properties. Our observations provide a deeper understanding of the self-assembly of CB[8] complexes, with fundamental implications in the design of functional 2D systems and crystalline materials. J Am Chem Soc . 2019 Sep 11;141(36):14021-14025. https://hdl.handle.net/20.500.12105/25090 31422657 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY BLOCK DNA CUCURBITURIL AMPHIPHILES NETWORKS KINETICS Emerging Two-Dimensional Crystallization of Cucurbit[8]uril Complexes: From Supramolecular Polymers to Nanofibers.