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00925njm 22002777a 4500 dc Ghosh, Kousik author Sil, Sayantan author Ray, Partha Pratim author Ortega-Castro, Joaquin author Frontera, Antonio author Chattopadhyay, Shouvik author 2019-10-30 The opto-electronic properties of an X-ray characterized, end-to-end azide bridged cobalt(III)-sodium complex, [(N-3)CoLNa(N-3)](n), have been investigated in detail. The complex is found to be a direct semiconductor material as confirmed by determining the band gap of this complex by experimental as well as theoretical studies. The complex has also been used to construct a photosensitive Schottky device. Optical conductivity, calculated from the DFT study, has been used to analyze how the conductivity of the material changes upon illumination. The electrical conductivity and concomitantly, the photoconductivity of the material increase as a consequence of photon absorption. Ghosh K, Sil S, Ray PP, Ortega-Castro J, Frontera A, Chattopadhyay S. Photosensitive Schottky barrier diode behavior of a semiconducting Co(III)-Na complex with a compartmental Schiff base ligand. RSC Adv. 2019 Oct 30;9(60):34710-9. http://hdl.handle.net/20.500.13003/9652 https://hdl.handle.net/20.500.12105/22802 35530669 10.1039/c9ra06354d 2046-2069 RSC Advances 2-s2.0-85074717479 498844000004 Photosensitive Schottky barrier diode behavior of a semiconducting Co(III)-Na complex with a compartmental Schiff base ligand