2026-04-28T21:35:20Zhttps://repisalud.isciii.es/rest/oai/requestoai:repisalud.isciii.es:20.500.12105/226352024-11-29T02:35:47Zcom_20.500.12105_15322com_20.500.12105_2051col_20.500.12105_16967
Repisalud
author
Hossain, Anowar
author
Dey, Arka
author
Seth, Saikat Kumar
author
Ray, Partha Pratim
author
Ballester, Pablo
author
Pritchard, Robin G
author
Ortega-Castro, Joaquin
author
Frontera, Antonio
author
Mukhopadhyay, Subrata
2024-09-06T09:56:44Z
2024-09-06T09:56:44Z
2018-08
Hossain Anowar, Dey Arka, Seth Saikat Kumar, Ray Partha Pratim, Ballester Pablo, Pritchard Robin G., et al. Enhanced Photosensitive Schottky Diode Behavior of Pyrazine over 2-Aminopyrimidine Ligand in Copper(II)-Phthalate MOFs: Experimental and Theoretical Rationalization. ACS Omega. 2018 Aug;3(8):9160-9171.
2470-1343
http://hdl.handle.net/20.500.13003/9177
https://hdl.handle.net/20.500.12105/22635
31459050
10.1021/acsomega.8b01111
Acs Omega
2-s2.0-85051730671
444182900057
Two novel Cu(II)-based metal-organic frameworks [C40H34Cu2N6O18 (1) and C20H18CuN2O10 (2)] have been synthesized using 2-ammopyrimidine or pyrazine ligands and phthalate ion and characterized spectroscopically and by X-ray single-crystal diffraction. Both 1 and 2 show electrical conductivity and photosensitivity, evidencing their potentiality in optoelectronic device applications. Experimental and theoretical investigations revealed that the electrical conductivity under irradiation of visible light increases compared to that under dark condition (photosensitive Schottky barrier diode behavior), especially in complex 2. Both 1 and 2 have been successfully applied in technologically challenging thin-film active devices.
eng
Enhanced Photosensitive Schottky Diode Behavior of Pyrazine over 2-Aminopyrimidine Ligand in Copper(II)-Phthalate MOFs: Experimental and Theoretical Rationalization
research article